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P-mSA/mCS双极膜的制备及其在一价、二价离子分离中的应用
双极膜 磷酸化 二茂铁 一价、二价离子的分离
2009/11/30
以五氧化二磷、磷酸三乙酯和磷酸为反应剂, 制备了磷酸化海藻酸钠(P-SA), 经二茂铁离子改性后作为阳膜层(P-mSA); 用乙酰基二茂铁改性壳聚糖制备了阴膜溶胶(mCS). 将阴膜溶胶流延于阳膜层上, 制备了P-二茂铁-SA/乙酰基二茂铁-CS双极膜(P-mSA/mCS BPM). 测定了双极膜的红外光谱、接触角、电荷密度、离子交换容量与交流阻抗. IR与接触角的分析结果表明, SA经磷酸化后,...
Gaseous(DMS, MSA, SO2, H2SO4 and DMSO)and particulate(sulfate and methanesulfonate)sulfur species over the northeastern coast of Crete
MSA SO2 H2SO4 DMSO northeastern coast of Crete
2009/3/11
A detailed study of the levels, the temporal and diurnal variability of the main compounds involved in the biogenic sulfur cycle was carried out in Crete (Eastern Mediterranean) during the Mediterrane...
DMS and MSA measurements in the Antarctic Boundary Layer: impact of BrO on MSA production
DMS MSA Antarctic Boundary Layer BrO MSA
2008/11/10
In situ measurements of dimethyl sulphide (DMS) and methane sulphonic acid (MSA) were made at Halley Station, Antarctica (75°35' S, 26°19' W) during February 2004–February 2005 as part of the CHABLIS ...
Ni-mSA-mCS双极膜的制备及其在电合成TGA中的应用
电合成 巯基乙酸 二硫代二乙酸 Ni-mSA-mCS双极膜
2010/1/22
通过用Ca2+改性海藻酸钠(SA)和用戊二醛改性壳聚糖(CS)制备Ni-mSA-mCS(m: modified)双极膜. 镍网预先埋在mSA膜表面作为阴极, 不仅增强了膜的机械性能, 而且降低阴极电解液的IR降, 实现零极距. 测定了膜的红外光谱、电镜扫描、机械性能. 将Ni-mSA-mCS双极膜应用于电还原制备巯基乙酸(TGA). 实验结果表明, 电流密度为10 mA·cm-2, 常温电解, 电...
含水混合溶剂中HCl活度系数的MSA计算
Mean sphere approximation Pitzers equation Activity coefficient HCl Aqueous-nonaqueous media
2010/2/3
含水混合溶剂中HCl活度系数的MSA计算。