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Solvent-Induced Infrared Frequency Shifts in Aromatic Nitriles are Quantitatively Described by the Vibrational Stark Effect
Nitriles Spectroscopy,Fourier Transform Infrared Vibration Static Electricity Solvents
2016/5/25
The physical properties of solvents strongly affect the spectra of dissolved solutes, and this phenomenon can be exploited to gain insight into the solvent-solute interaction. The large solvatochromic...
Large Protein-Induced Dipoles for a Symmetric Carotenoid in a Photosynthetic Antenna Complex
Bacterial Proteins Carotenoids Cell Membrane Chemistry, Physical Macromolecular Substances Membrane Potentials Membrane Proteins Photosynthesis Physicochemical Phenomena Rhodobacter sphaeroides Solvents Spectrum Analysis
2016/5/23
Unusually large electric field effects have been measured for the absorption spectra of carotenoids (spheroidene) in the B800-850 light-harvesting complex from the photosynthetic bacterium Rhodobacter...