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Distance Dependence of Electron-Transfer Reactions in Organized Systems:The Role of Superexchange and Non-Condon Effects in Photosynthetic Reaction Centers
Distance Dependence Electron-Transfer Reactions Organized Systems Superexchange Non-Condon Photosynthetic Reaction Centers
2016/5/23
Extremely long distance electron transfer is observed in some photosynthetic reaction centers. For several charge recombination reactions, the rate appears to fall off much more slowly with distance t...
Peculiar long-range superexchange in Cu2A2O7 (A = P, As, V): a spectacle of anions
Peculiar long-range superexchange spectacle of anions
2010/11/25
A microscopic magnetic model for -Cu2P2O7 is evaluated in a combined theoretical and ex-
perimental study. Despite a dominant intradimer coupling J1, sizable interdimer couplings enforce magnetic or...