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A method was developed for the determination of trace amounts of Al species in water samples using the amberlite type XAD-4 resin. For this purpose, total dissolved Al, organically bonded Al and parti...
As acidic water percolates through mineral soils, Al is mobilized and transported into streams and lakes. We evaluate the effect of increasing temperature (climate warming) on Al concentrations in fou...
In this work, the corrosion behavior of iron and aluminum was investigated in 0.1 M NaCl solutions with an initial pH value of 8 and containing various concentrations (0, 30, 150, 300 ppm) of benzoic ...
Abstract: OH-Al solutions were prepared by adding appropriate amounts of NaOH to AlCl3 to obtain OH/Al mole ratios of 2.0, 2.5, 2.7, 3.0, and 3.3 in the final suspension. Solid Na2SO4 and Georgia kaol...
Acid precipitation has been shown to reduce phosphorus (P) outputs from terrestrial sources. We present field evidence that the in-lake P cycle may also be disrupted in atmospherically acidified water...
Background: Soluble silica, a ubiquitous component of the diet, may be the natural ligand for dietary aluminum and may prevent its accumulation and toxicity in animals. However, previous studies on...
Abstract: Oxygen-isotope data were obtained for synthetic aluminum-hydroxide phases precipitated over 65–125 mo and have been compared to results from similar experiments conducted for 3–56 mo. The Al...
Abstract: Samples of Silica Springs allophane from Tongariro National Park, New Zealand, having Al/Si atomic ratios in the range 1.1–1.9, were studied by 27Al nuclear magnetic resonance (NMR) spectros...
Abstract: Double hydroxide solids precipitated homogeneously from three laboratory-synthesized aqueous solutions that simulated mildly contaminated surface or groundwater. Over a limited pH range, pre...
Ab initio, molecular orbital calculations for two different Hartree-Fock basis levels were performed on clusters in the system Al-O-H, and tested by comparing derived vibrational frequencies to the me...
An atomistic computer simulation study was undertaken to address the role of Al in the substitution of ferric iron into magnesium silicate perovskite, MgSiO 3. Calculated substi-tution and vacancy en...
Abstract: The Crystal Packer module in the Cerius2 modeling environment has been used to study the structure of montmorillonite intercalated with Al(OH)3-fragment (gibbsite-like) polymers. Basal spaci...
Abstract: The structure of montmorillonite intercalated with [Al13O4(OH)24+x(H2O)12−x](7−x)+ cations ( A l 13 (7−x)+ for short), where x = 0, 2 and 4, has been studied using the Ceri...
Abstract: The hydrothermal synthesis of Mg-beidellite in which limited amounts of Ga and Cr are clearly shown to be incorporated into nonexchangeable positions in the clay layer framework is reported ...

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