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Hydroxy-Al- and hydroxy-Mg-montmorillonite were prepared by treating dispersed Na-montmorillonite with aluminum and magnesium nitrate solutions and titrating with NaOH solutions so that the OH/Al rati...
Abstract: Hydrotalcite solid solutions were prepared by coprecipitation followed by hydrothermal treatment between 150° and 250°C. Based on the structural formula [Mg1−xAlx(OH)2]X+[(CO3)x/2ͺ...
Biotite in deeply weathered granitic rocks in southwestern Australia has altered to exfoliated grains composed of biotite, mixed-layer clay minerals, kaolinite, vermiculite, gibbsite, goethite, and he...
When aqueous dispersions of Na+-smectite or n-butylammonium-vermiculite react with sulfate salts of Fe(II), Co(II), or Ni(II) bipyridyl or 1, 10-phenanthroline complexes in excess of the cation-exchan...
Natural erionite was exhaustively ion exchanged with Na+ to give the anhydrous unit-cell composition (K1.9Na5.4Ca0.1Mg0.1)[(AlO2)7.4(SiO2)28.6]. A thermodynamic study of alkali and alkaline earth meta...
Montmorillonite-aminocaproic acid complexes (monomer complexes) were prepared by the intercalation of 6-aminocaproic acid to various homoionic (Na+, Ca2+, Mg2+, Co2+, and Cu2+) montmorillonites. Infra...
Aluminum-substituted hematites (Fe2−xAlxO3) were synthesized from Fe-Al coprecipitates at pH 5.5, 7.0, and in 10−1, 10−2, and 10−2 M KOH at 70°C. As little as 1 mole % Al suppr...
“Kaolinites” from classic, large deposits of kaolin are shown commonly in scanning electron micrographs to be mixtures, at least in part, in microdimensions, of kaolin-mineral polymorphs.Artificial mi...
A stable porous system consisting of montmorillonite cross-linked by Al-hydroxide oligomers was synthesized by reacting at room temperature an aqueous solution of such oligomers with a unit-layer disp...
Abstract: Hydrotalcite-like compounds [MgI − xAlx(OH)2]x+ [Ax/22−, mH2O]x−, where A2− is SO42− or CrO42− and x ≇ 0.25, were prepared by a coprecipitation meth...
Sesquioxidic soil clays from Oxisols in South Africa, Australia and Brazil, and two clays from Andosols in Japan and New Zealand, were investigated by selective dissolution techniques. Acid ammonium o...
Nine synthetic Na-saponites with charge densities varying between 0.33 and 1.0 have been prepared. Their swelling properties and structural organization in water, ethylene glycol and glycerol show dis...
Crystallographic properties of illite and chemical properties of organic matter in various mudstones ranging in age from Archean to Miocene were investigated. The breadth of the (001) X-ray powder dif...
Abstract: The electron structural analysis of a Madagascar sepiolite (Ampandrandava) was carried out by selected area electron diffraction obtained from monocristals. Fourier projections, derived from...
The basic salts of this system were prepared and their structures and physico-chemical properties were studies by electron microscopy, chemical analysis, X-ray powder diffraction, thermal analysis, i....

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