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Abstract: Terra rossa samples were taken from the B horizons of soil profiles and from cracks within limestone in Italy. The average annual temperature (AAT) of the sites ranged from 8.4 to 20.3°C and...
Fe(II) and Fe(III) in various proportions were coprecipitated by NH3 at pH ≈ 11. The Fe(II)/Fe(III) ratio (x) was varied from 0.10 to 0.50. After stabilization by aging at pH ≃ 8 in anaerobic co...
Synthetic hematites with Al substitutions between 0 and 18 mol % were synthesized at different temperatures and water activities. The cell-edge lengths a for different synthesis conditions decreased l...
Abstract: The rate of Fe(II) oxidation at a constant rate of oxygen supply in the presence of citrate was measured at pH 6.0 at various citrate/Fe(II) molar ratios at 23.5°C in 0.01 M ferrous perchlor...
The influence of added sodium and calcium nitrate electrolyte on the particle aggregates in the colloid fraction of natural bentonite and kaolin was studied. Clays were flocculated in distilled water ...
Abstract: Contact angles of glycerol and diiodomethane drops were measured on the surface of kaolin pellets covered with different amounts of dodecylamine chloride (DDACl) to as much as one monolayer....
Lepidocrocite samples, γ-FeOOH, containing 0–10 mole % Al-for-Fe substitution were synthesized at 15°C and pH 8 by oxidizing mixed FeCl2-AlCl3 solutions. The unit-cell parameters a, b, and c were meas...
Mixtures of magnetite and goethite were formed by the slow oxidation of mixed FeCl2-AlCl3 solutions in an alkaline environment at room temperature. The compositions of the products ranged from almost ...
Effects of clay content on saturated hydraulic conductivities (k) of two coarse textured soils, Vista (mixed thermic Typic Xerochrepts) and Hanford (mixed nonacid Typic Xerorthents), and a medium text...
Raman and Fourier-transform-infrared (FTIR) spectroscopic methods and X-ray powder diffraction (XRD) techniques have been used to study the influence of hydrazine on the vibrational modes of kaolinite...
The influence of Mn2+ on the formation of Fe oxides at pHs of 6.0 and 8.0 and varying Mn/Fe molar ratios (0, 0.1, 1.0, and 10.0) in the FeCl2-NH4OH and FeSO4-NH4OH systems was studied by X-ray powder ...
The transformation of ferrihydrite to goethite and/or hematite, as influenced by the presence of co-precipitated Si, was investigated by infrared spectroscopy (IR), X-ray powder diffraction (XRD), and...
The influence of adsorbed H+, Na+, K+, Ca2+, Mg2+, Ba2+, and Al3+ ions on the wettability of a kaolinite surface was determined from contact angles, which were measured in kaolinite-water drop- air (s...
The influence of manganese oxide minerals (cryptomelane, hausmannite, and pyrolusite) on the formation of iron oxides was studied in the FeCl2-NH4OH system at different Mn/Fe molar ratios (0, 0.01, 0....
A series of synthetic goethites containing varying amounts of Si and P dopants were characterized by X-ray powder diffraction, electron diffraction, microbeam electron diffraction, and M鰏sbauer spectr...

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