搜索结果: 61-75 共查到“知识库 有机合成化学”相关记录1973条 . 查询时间(1.218 秒)
A new dinuclear lead(II) complex of 2,3-diphenyl-tetrazole-5-thione: synthesis and characterization
Lead complex tetrazole-5-thione crystal structure
2010/10/19
The present work reports on the synthesis, crystal structure, fluorescence, electrochemical behavior, and thermogravimetric analysis of a new dinuclear lead(II) complex of 2,3-diphenyl-tetrazole-5-thi...
Silica supported polyphosphoric acid (PPA-SiO2): an efficient and reusable heterogeneous catalyst for the one-pot synthesis of a -amino phosphonates
a -Amino phosphonates PPA-SiO2 heterogeneous catalyst
2010/10/19
An efficient green protocol is described for the preparation of a -amino phosphonates, employing a one-pot three-component condensation reaction between aldehydes, amines, and trialkyl phosphites in t...
(E)-3-[(3-(Trifluoromethyl)phenylimino)methyl] benzene-1,2-diol: X-ray and DFT calculated structures
Schiff bases phenol-imine X-ray crystal structure IR DFT
2010/10/18
The crystal structure of (E)-3-[(3-(Trifluoromethyl)phenylimino)- methyl]benzene-1,2-diol was determined using X-ray diffraction and the molecular structure was investigated with density functional th...
Electrochemical properties of 1-(o-, m-, p-nitrophenyl)-3-(m-nitrophenyl)- 5-phenylformazans and their nickel complexes
Formazans nickel complexes spectroscopy substituent effect
2010/10/18
The electrochemical properties of NO2 formazans and their Ni(II) complexes were investigated. The investigated formazans included a NO2 group at the o-, m-, and p-positions of the 1-phenyl ring and at...
Evaluation of solid-phase extraction sorbent with ketoimine groups for the preconcentration of benzene and phenolic compounds in water
Modified silica solid-phase extraction SPE
2010/10/18
The applicability of silica gel, modified with ketoimine groups, to solid phase extraction (SPE) was tested. Basic characteristics of the modified silica were determined using elemental analysis, and ...
Mannich base derivatives of 3-hydroxy-6- methyl-4H-pyran-4-one with antimicrobial activity
Antimycobacterial and antibacterial activity DNA gyrase activity
2010/10/18
A series of 3-hydroxy-6-methyl-2-[(substitutedpiperidine-1-yl) methyl]-4H-pyran-4-one structured compounds were synthesized by reacting 5-hydroxy-2-methyl-4H-pyran-4-one with suitable piperidine deriv...
Synthesis and characterization of hybrid congo red from chloro-functionalized silsesquioxanes
Ceramic dye hybrid dye POSS congo red
2010/10/18
Congo red dye has been bonded to the functionalized octameric polyhedral silsesquioxanes (POSS), which were prepared by hydrolytic condensation of chloro-functionalized organosilicon monomers in the p...
Synthesis, characterization, antibacterial and antifungal evaluation of some new platinum(II) complexes of 2-phenylbenzimidazole ligands
Antibacterial activity antifungal activity benzimidazole
2010/10/18
A series of platinum(II) complexes of the type [PtL2Cl2] 1, [PtL2I2] 2, [PtL2(oxalato)] 3, and [PtL2(malonato)] 4 (L= 2-phenylbenzimidazole ligands as ``non-leaving groups'') were synthesized and cha...
Molecular recognition of aromatic amines by coumarin substituted azacrown ether
Chromogenic azacrown ether primary aromatic amines
2010/10/18
New chromogenic azacrown ether N[7-hydroxy-4-methyl-coumarin-8-methylene]-4-azadibenzo-18-crownether (HMCMADCE) was synthesised through the condensation reaction of 4-azadibenzo-18-crown- 6ether, 4-me...
An efficient one-pot synthesis of dihydropyrimidinones catalyzed by zirconium hydrogen phosphate under solvent-free conditions
Biginelli reaction solvent-free zirconium hydrogen phosphate
2010/10/18
A simple, efficient, and practical procedure for the Biginelli reaction using zirconium hydrogen phosphate [Zr(H2PO4)2] as a novel solid acid catalyst is described under solvent-free conditions in hig...
A theoretical study of the effects of polar substitution on the activation barriers for internal rotation around the C-N bond in p-substituted nitrosobenzenes: comparison of DFT and MP2 calculations
Para-substituted nitrosobenzenes C-N bond rotation polar substituent effect
2010/10/18
The activation barriers for internal rotation around the C-N bond in p-substituted nitrosobenzenes were calculated using the density functional theory (DFT) and second-order Møller-Plesset (MP2...
Asymmetric synthesis of 8-O-4'-neolignan perseal B
Neolignans perseal B enantioselective synthesis
2010/10/18
Full details of an enantioselective total synthesis of 8-O-4'-neolignan perseal B are presented for the first time. The synthesis was achieved in 8 steps from vanillin and involved the asymmetric dihy...
An efficient synthesis of Schiff bases containing benzimidazole moiety catalyzed by transition metal nitrates
Aldehyde 2-aminobenzimidazole catalyst Schiff bases
2010/10/18
A simple and efficient method has been developed for the synthesis of some novel Schiff bases via the reaction of aromatic aldehydes with 2-aminobenzimidazole by using catalytic amount of M(NO3)2.xH2O...
Convenient synthesis of monomeric steroids from steroidal oxalate dimers using flash vacuum pyrolysis (FVP)
Steroid oxalate dimers steroidal alkene diene triene
2010/10/18
Flash vacuum pyrolysis (FVP) or thermolysis (FVT), an environmentally friendly method for studying organic reaction mechanisms as well as synthesis, was applied to a series of oxalate dimers (1, 3, 5,...
Synthesis and antimicrobial activities of 2-(5-mercapto)-1,3-oxadiazol-2-ylmethyl-1,2,4-triazol-3-one derivatives
1,2,4-Triazole 1,3,4-oxadiazole Mannich base antimicrobial activity
2010/10/18
The synthesis of 4-amino-2-[(5-mercapto-1,3,4-oxadiazol-2- yl)methyl]-5-(4-methylphenyl)-2,4-dihydro-3H-1,2,4-triazol-3-one (2) and 4-amino-2-[(4-amino-5-mercapto-4H-1,2,4-triazol-3-yl)methyl]- 5-(4-m...