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Synthesis of (+)-(S)-isorobinal together with its antipod, a cyclic monoterpene functioning as the sex pheromone of Rhizoglyphus setosus and its distribution among Astigmata
mite Astigmata Rhizoglyphus sp. isorobinal 4-isopropenyl-3-oxo-1-cyclohexene-1-carbaldehyde
2009/3/5
Both compounds, (+)-(S)- and (−)-(R)-4-isopropenyl-3-oxo-1-cyclohexene-1-carbaldehyde [(+)-(S)- and (−)-(R)-isorobinal, (S)- and (R)-1, [α]D28 +51° (c=1.0, CHCl3) and [α]D25 −45° (...