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Hydration Kinetics of Quicklime.
Abstract: Smectites synthesized from experiments at 5.5 GPa and 1500癈 are of high quality, crystals are large at >10 祄, and the 2:1 layers may have a homogeneous charge distribution. Smectite was exch...
Abstract: Reduction of structural Fe in Na-exchanged dioctahedral smectites decreases swellability in water, but because clay interlayers also collapse in the process the concomitant effect on surface...
Abstract: The objective of this study was to investigate the influence of layer charge on the hydration of Mg-saturated expandable 2:1 phyllosilicates. Water retained by 12 Mg-saturated clays at 54% r...
Abstract: The application of the Frenkel-Halsey-Hill (FHH) formalism to the water desorption isotherms obtained for the whole range of the activity of water with the pressure membrane device (0.98 < a...
Abstract: The enthalpy of hydration of natural clinoptilolite was determined by isothermal immersion calorimetry on Ca-, Na- and K-exchanged clinoptilolite (Fish Creek Mountains, Nevada). Heats of imm...
Abstract: Hydration behavior of Na-smectite crystals synthesized at a pressure of 5.5 GPa and temperatures of 1400°–1500°C was examined by X-ray powder diffraction at various relative humidities (RH) ...
A high-pressure, high-temperature cell was used to monitor the basal X-ray powder diffraction spacing of Na-saturated Cheto montmorillonite in contact with NaCl solutions at temperatures as high as 20...
Electron spin resonance (ESR) spectra of Cu2+-hexadecylpyridinium (HDP) montmorillonites were investigated as a function of HDP+ content and the hydration state of Cu2+ at relative humidities of p/p0 ...
Abstract--The structure and hydration status of attapulgite clay after heating at elevated temperatures and the stability of parathion on these clays was studied. Using infrared spectroscopy and scann...
The frequencies of structural OH stretching vibrations in swelling trioctahedral minerals such as hectorite or K-depleted phlogopite depend on the ionic form and hydration of the sample. The trioctahe...
Equilibrium studies on clay films exposed to NH3 and H2O vapors demonstrate the effect of exchangeable cations on surface acidity and its relationship to hydration. At a relative humidity of 98 per ce...
Abstract: Previous investigations have demonstrated the influences of interlayer cation composition, relative humidity, temperature, and magnitude of interlayer surface charge on the interlayer hydrat...
Previous studies of diffraction band profiles of montmorillonite are extended to the 13, 20 band which, for reasons discussed, is more sensitive to structural details than the diffraction bands consid...

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