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Clay minerals possess sorptive capacities for organic and inorganic matter, including DNA (Lorenz and Wackernagel, 1994), and hence reduce the utilization and degradation of organic matter or DNA by m...
Abstract: The dielectric behavior of kaolinite, montmorillonite, allophane, and imogolite samples adjusted to a water potential of 33 kPa was examined using a time-domain reflectometry method over a w...
Abstract: Samples of Silica Springs allophane from Tongariro National Park, New Zealand, having Al/Si atomic ratios in the range 1.1–1.9, were studied by 27Al nuclear magnetic resonance (NMR) spectros...
Abstract: Water retention curves of colloidal allophane and imogolite with different charges and different pretreatments were measured using a tension plate and a pressure plate apparatus. An irrevers...
Abstract: Aqueous suspensions of allophane show relatively high viscosity, presumably because of strong particle interaction between the unit particles. To test this hypothesis, we measured the partic...
The purpose of this study was to investigate bonding mechanisms of representative inorganic anions and citrate with imogolite and allophane using electrophoresis. The electrophoretic mobility (EM) of ...
Experimental alteration of volcanic glass has been carried out in distilled water at 200°C and 150°C. The formation and transformation processes of alteration products have been examined by scanning e...
Solutions containing AlCl3 and Si(OH)4 (concentrations ≤ 1.5 mM with molar Si:Al ratios of 1:2, 1:1 and 3:1) and FeCl2 (0, 0.5 and 1.0 mM) were adjusted to pH 8 with Ca(OH)2, and incubated at 23°C and...
The size distribution of unit particles of two New Zealand allophanes (An and Rh), in dilute (0.8% w/v) aqueous suspensions, has been determined by small-angle neutron scattering (SANS). In addition, ...
Small-angle X-ray powder diffraction analyses and high-resolution electron microscopy of allophane samples (SiO2/Al2O3 ratio, 1.12 to 1.68) showed that allophanes consist of nearly identical spherical...
Adsorption of Cu2+ and Co2+ by synthetic imogolite, synthetic allophanes with a range of SiO2/Al2O3 ratios, and allophanic clay fractions from volcanic ash soils was measured in an ionic medium of 0.0...
The negative surface charge of synthetic allophanes with a range of Si/Al ratios decreased and positive charge increased with increasing alumina content at a given pH. The phosphate adsorption capacit...
The adsorption of sodium, chloride, and phosphate ions by allophane, imogolite, and halloysite has been studied in relation to the surface structure of the mineral samples. The high adsorption of phos...
Allophanes with SiO2/Al2O3 molar ratios from 1.38 to 1.92 were heated at temperatures up to 500°C, and the changes induced were investigated by means of infrared spectroscopy (IR) and X-ray powder dif...
Samples containing allophane with molar Al/Si ratios from 1.0 to 2.0 have been examined by infrared spectroscopy, X-ray fluorescence, and phosphate adsorption methods. The infrared spectra of allophan...

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