搜索结果: 1-15 共查到“理学 Stark effect”相关记录22条 . 查询时间(0.08 秒)
Measuring Electric Fields and Noncovalent Interactions Using the Vibrational Stark Effect
Organic Chemicals Proteins Vibration Models,Molecular Static Electricity
2016/5/25
Over the past decade, we have developed a spectroscopic approach to measure electric fields inside matter with high spatial (<1 Å) and field (<1 MV/cm) resolution. The approach hinges on exploiti...
Solvent-Induced Infrared Frequency Shifts in Aromatic Nitriles are Quantitatively Described by the Vibrational Stark Effect
Nitriles Spectroscopy,Fourier Transform Infrared Vibration Static Electricity Solvents
2016/5/25
The physical properties of solvents strongly affect the spectra of dissolved solutes, and this phenomenon can be exploited to gain insight into the solvent-solute interaction. The large solvatochromic...
Electrostatic Fields Near the Active Site of Human Aldose Reductase:1.New Inhibitors and Vibrational Stark Effect Measurements
apoptosis ATM cisplatin IKK p73 ubiquitination
2016/5/25
Vibrational Stark effect spectroscopy was used to measure electrostatic fields in the hydrophobic region of the active site of human aldose reductase (hALR2). A new hALR2 inhibitor was designed and sy...
Vibrational Stark Effect Probes for Nucleic Acids
ternary complex precipitation europium pyridine-2,6-dicarboxylate fluorescence
2016/5/24
The vibrational Stark effect (VSE) has proven to be an effective method for the study of electric fields in proteins via the use of infrared probes. To explore the use of VSE in nucleic acids, we inve...
Intervalence Band Stark Effect of the Special Pair Radical Cation in Bacterial Photosynthetic Reaction Centers
alloys low index single crystal surfaces low energy electron diffraction (LEED) scanning tunneling microscopy X-ray standing waves surface relaxation and reconstruction tin copper
2016/5/24
The Stark spectrum of the intervalence band of the special pair radical cation in bacterial photosynthetic reaction centers is presented. This spectrum, centered at 2600 cm-1, is modeled using a gener...
Stark Effect Spectroscopy of the Heme Charge Transfer Bands of Deoxymyoglobin
materials science electronic structure oxygen compounds myoglobin charge transport stark effect absorption spectra spectroscopy heme protoporphyrins
2016/5/23
We report the Stark spectra of the Soret, Q, and charge-transfer bands of deoxymyoglobin. The data show that band III has charge-transfer character but that the magnitude of the charge displacement is...
Effects of Applied Electric Fields on the Quantum Yields for the Initial Electron Transfer Steps in Bacterial Photosynthesis:II.Dynamic Stark Effect
Applied Electric Fields Quantum Yields Initial Electron Transfer Steps Bacterial Photosynthesis Dynamic Stark Effect
2016/5/23
The quantum yield of the initial charge separation steps in bacterial photosynthetic reaction centers has been shown to be reduced in an applied electric field [Part I, Lao et al., J. Phys. Chem. 97 (...
Stark Effect Spectroscopy of Tryptophan
Biophysical Phenomena Biophysics Electrochemistry Fluorescence Polarization Melitten Models,Chemical Photochemistry Solvents Spectrometry, Fluorescence Spectrophotometry Tryptophan Tryptophan
2016/5/23
The change in permanent dipole moment (magnitude of delta mu) for the transition from the 1La state to the ground state of tryptophan is the key photophysical parameter for the interpretation of trypt...
Vibrational Stark Effect Spectroscopy.
Stark Effect Spectroscopy of the 1250 nm P+ Band of Rhodobacter sphaeroides Reaction Centers and Related Model Compounds
Photosynthesis Reactioncenter Stark spectroscopy Mixedvalence
2016/5/23
The absorption and Stark effect spectra of the 1250 nm hand associated with the oxidized special pair (P+) in Rhodobacter sphaeroides reaction centers have been measured. The absorption spectrum in th...
Stark Effect (Electroabsorption) Spectroscopy of Photosynthetic Reaction Centers at 1.5 K:Evidence that the Special Pair has a Large Excited-State Polarizability
Photosynthesis Reaction center Stark spectroscopy Specialpair
2016/5/23
The Stark effect or electroabsorption spectrum of the Qy transition of the special pair, P, of Rb. sphaeroides reaction centers has been measured at 1.5 K in frozen glycerol/buffer glasses. Under thes...
Studies of Crystalline Aggregates of Pheophorbide and Bacteriopheophorbide by Electro-Absorption (Stark Effect) Spectroscopy and Powder X-ray Diffraction
GYROTRON 2ND HARMONIC SUBMILLIMETER WAVE
2016/5/23
Absorption and electro-absorption (Stark effect) spectra of polycrystalline and lyophillized samples of pheophorbides and bacteriopheophorbides have been measured in order to obtain information on the...
Stark Effect Spectroscopy of Carotenoids in Reaction Center and Antenna Complexes from Photosynthetic Bacteria
Stark effect Electric field effect Carotenoid Carotenoid bandshift
2016/5/23
The effects of electric fields on the absorption spectra of the carotenoids spheroidene and spheroidenone in photosynthetic antenna and reaction center complexes (wild-type and several mutants) from p...
Stark Effect Spectroscopy of Bacteriochlorophyll in Light-harvesting Complexes from Photosynthetic Bacteria
Stark effect Electric field effect Antenna complex Light harvesting complex Energy transfer BCP bacteriochlorophyll a protein RC reaction center
2016/5/23
The effects of an applied electric field on the Q y absorption and fluorescence spectra of three antenna complexes from photosynthetic bacteria have been measured at 77 K: the bacteriochlorophyll a pr...
Electroabsorption (Stark Effect) Spectroscopy of Mono-and Biruthenium Charge-Transfer Complexes:Measurements of Changes in Dipole Moments and Other Electrooptic Properties
PERVAPORATION REVERSE OSMOSIS SEPARATION OF AMYL ALCOHOL WATER MIXTURES POLY(VINYL ALCOHOL) POLYACRYLONITRILE COMPOSITE MEMBRANES POLYAMIDE POLYETHERSULFONE COMPOSITE MEMBRANES
2016/5/23
Electroabsorption (Stark effect) spectra are reported for the charge-transfer transitions of (NH3)5RuL2+ and [(NH3)5Ru]2L4+,5+, where L is pyrazine (pz) or 4,4'-bipyridine (4,4'-bpy). The spectra perm...