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用非等温热重法考察了潞安煤焦的水蒸气气化反应，分析了升温速率及水蒸气分压改变对煤焦气化反应性的影响。动力学计算结果表明：潞安煤焦气化行为可用体积反应模型来描述；通过求取的动力学参数可以发现，活化能与指前因子存在明显的动力学补偿效应，补偿效应可由过渡态理论给予解释。
Characterization of the Luminescent, Homoleptic, Three-Coordinate, Water Soluble Au(I) Complex of Trisulfonated Triphenylphosphine（TPPTS）as the Cesium Salt, Cs8[Au(TPPTS)3].5.25 H2O
Triphenylphosphine Cesium Salt
2009/7/29
The homoleptic metal-TPPTS complex Cs8[Au(TPPTS)3].5.25 H2O has been characterized structurally. The x-ray data for the triclinic crystal, P-1, with cell constants a = 13.7003(4), b = 18.0001(6), c = ...
Hybrid Density functional calculations have been
carried out for Au10, Au10-H2O, Au10-O2, and Au10-H2
O-O2 model clusters. The results show that all the
Au10 clusters examined have a weak interacti...