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Effects of pH, Eu(III) concentration, ionic strength, temperature and humic acid (HA) on Eu(III) sorption to iron oxides were investigated in detail. The sorption of Eu(III) to iron oxides was signifi...
Iron oxide and hydroxides can be precipitated from solution with both Fe21 and Fe31 states by a microbial consortium enriched from surface water draining a granitic batholith. The Fe21/Fe31 ratio of t...
Abstract: Solid phase transformation and metal solubility were monitored after coprecipitation of Cd2+, Cu2+, Pb2+ and Zn2+ with Fe3+ to form ferrihydrite by titration to pH 6. The (co)precipitates we...
Abstract: A dusky red Oxisol forming on a tholeiitic basalt is found to contain varying proportion of aluminous hematite (Hm) and titanoaluminous maghemite (Mh) in the different size fractions. Maghem...
Abstract: Surface adsorption mechanisms of dissolved inorganic carbon species on soil minerals are not well understood. Traditional infrared (IR) study of adsorbed species of inorganic carbon using ai...
Synthetic hematites with Al substitutions between 0 and 18 mol % were synthesized at different temperatures and water activities. The cell-edge lengths a for different synthesis conditions decreased l...
A new iron oxide dissolution method designed to measure the abundance of “free” Fe oxide phases and associated elements in soils and sediments has been tested. The method employs a ternary complex of ...
Lepidocrocite samples, γ-FeOOH, containing 0–10 mole % Al-for-Fe substitution were synthesized at 15°C and pH 8 by oxidizing mixed FeCl2-AlCl3 solutions. The unit-cell parameters a, b, and c were meas...
Mixtures of magnetite and goethite were formed by the slow oxidation of mixed FeCl2-AlCl3 solutions in an alkaline environment at room temperature. The compositions of the products ranged from almost ...
Abstract: At pH 12 Co-ferrihydrite transformed to either Co-goethite or Co-magnetite, the latter compound appearing at Co additions of > 18 mole %. Although Co was readily taken up by the magnetite st...
The influence of Mn2+ on the formation of Fe oxides at pHs of 6.0 and 8.0 and varying Mn/Fe molar ratios (0, 0.1, 1.0, and 10.0) in the FeCl2-NH4OH and FeSO4-NH4OH systems was studied by X-ray powder ...
The influence of manganese oxide minerals (cryptomelane, hausmannite, and pyrolusite) on the formation of iron oxides was studied in the FeCl2-NH4OH system at different Mn/Fe molar ratios (0, 0.01, 0....
Iron impurities in the Hohen Hagen nontronite (NG-1) were identified as maghemite and goethite. The phase identified as maghemite was magnetically ordered at both room temperature and 87 K, with hyper...
The kinetics of hydroquinone oxidation by aqueous suspensions of pure hematite and goethite-ferrihydrite mixtures at pH 6.0, 7.4, and 9 was studied using an on-line analysis system. The electron trans...
Fifteen iron oxide accumulations from the bottoms of two Finnish lakes (搇ake ores? were found to contain as much as 50% Fe. Differential X-ray powder diffraction and selective dissolution by oxalate s...

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